First examples of dammarane triterpenes isolated from Celastraceae

Haydee Chávez, Ana Estévez-Braun, Ángel G. Ravelo, Antonio G. González

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27 Scopus citations

Abstract

Eight new dammarane triterpenes were isolated fro Maytenus Macrocarpa. Their structures were determined by means of 1H and 13C NMR spectroscopic studies, including 1H-13C heteronuclear correlation (HETCOR), long range correlation with inverse detection (HMBC), and chemical evidence. This is the first time that dammarane triterpenes have been isolated from Celastraceae.

Original languageEnglish
Pages (from-to)6465-6472
Number of pages8
JournalTetrahedron
Volume53
Issue number18
DOIs
StatePublished - 5 May 1997
Externally publishedYes

Bibliographical note

Funding Information:
This work has been partly funded by the Spanish CICYT, project SAF 94-0239, and by the Gobierno Autonomo de Canarias. We thank Profs. J. Orduna, A.Hern~indez and T.Sierra for carrying out the HRMS, and to Prof. I.L. Bazzocchi for carrying out the 2D NMR spectrum. References and Notes Gonz~lez, A.G.; Jim6nez, J.S.; Moujir, L.M.; Ravelo A.G.; Lois, J.G.; Bazzocchi, I.L. and Navarro-Gutierrez, A.M. Tetrahedron, 1992, 48, 769-774. Gon~lez, A.G.; Alvarenga, N.L.; Est6vez-Braun, A.; Raveio A.G.; Bazzocchi, I.L.; Moujir, L.M.; Tetrahedron, 1996, 52, 9597-9608. Soukup J. Nombre Vulgares de la Flora Peruana; Editorial Salesianos: Lima. 1997. Gupta M.P. 270 Plantas Medicinales Iberoamericanos; Convemo Andres Bello: Colombia, Bogotfi.1995. GonzAlez, A.G.; Alvarenga, N.L.; Raveio A.G.; Bazzocchi, I.L.; Ferro, E.A.;Navarro-Gutierrez, A.M; Moujir, L.M.; Bioorg. Med, Chem., 1996, 4, 815-820. Borman S. Chem. andEng., 1996, 9. Zeng L.; Gu Z.; Fang X.P.; Fanwick P.F.; Chang C.; Smith D.L.; MacLaughlin J.L. Tetrahedron, 1996, 2477-2488. Smith-Kielland I.; Dornlsh J.M.; Malterud FLE.; Hvistendahl G.; Romming C.; Bockman O.C.; Kolsaker P.; Stenstrom Y.; Nordal A. Planta Med., 1996, 62, 322-325.

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